One-Electron (2c/1e) Tin···Tin Bond Stabilized by ortho-Phenylenediamido Ligands.

Odd-electron bonds, i.e., the two-center, three-electron (2c/3e), or one-electron (2c/1e) bonds, have attracted tremendous interest owing to their novel bonding nature and radical properties. Herein, complex [K(THF)6][LSn:···Sn:L] (1), featuring the first and unsupported 2c/1e Sn···Sn σ-bond with a long distance (3.2155(9) Å), was synthesized by reduction of stannylene [LSn:] (L = N,N-dpp-o-phenylene diamide) with KC8. The one-electron Sn-Sn bond in 1 was confirmed by the crystal structure, DFT calculations, EPR spectroscopy, and reactivity studies. This compound can be viewed as a stabilized radical by delocalizing to two metal centers and can readily mediate radical reactions such as C-C coupling of benzaldehyde.

Adulteration Detection of Pork in Mutton Using Smart Phone with the CBAM-Invert-ResNet and Multiple Parts Feature Fusion.

To achieve accurate detection the content of multiple parts pork adulterated in mutton under the effect of mutton flavor essence and colorant by RGB images, the improved CBAM-Invert-ResNet50 network based on the attention mechanism and the inversion residual was used to detect the content of pork from the back, front leg, and hind leg in adulterated mutton. The deep features of different parts extracted by the CBAM-Invert-ResNet50 were fused by feature, stitched, and combined with transfer learning, and the content of pork from mixed parts in adulterated mutton was detected. The results showed that the R2 of the CBAM-Invert-ResNet50 for the back, front leg, and hind leg datasets were 0.9373, 0.8876, and 0.9055, respectively, and the RMSE values were 0.0268 g·g-1, 0.0378 g·g-1, and 0.0316 g·g-1, respectively. The R2 and RMSE of the mixed dataset were 0.9264 and 0.0290 g·g-1, respectively. When the features of different parts were fused, the R2 and RMSE of the CBAM-Invert-ResNet50 for the mixed dataset were 0.9589 and 0.0220 g·g-1, respectively. Compared with the model built before feature fusion, the R2 of the mixed dataset increased by 0.0325, and the RMSE decreased by 0.0070 g·g-1. The above results indicated that the CBAM-Invert-ResNet50 model could effectively detect the content of pork from different parts in adulterated mutton as additives. Feature fusion combined with transfer learning can effectively improve the detection accuracy for the content of mixed parts of pork in adulterated mutton. The results of this study can provide technical support and a basis for maintaining the mutton market order and protecting mutton food safety supervision.

Brillouin gain spectrum characterization in an acoustic anti-guided delivery fiber for high power narrow linewidth laser.

The Brillouin gain spectrum (BGS) provides key information for stimulated Brillouin scattering (SBS), such as the Brillouin frequency shift (BFS), Brillouin spontaneous linewidth, and Brillouin gain coefficient. In this study, we theoretically investigate the field distributions and BGS characterization of Ge-doped, Al-doped, and Al/Ge co-doped fibers. Additionally, we analyzed and compared the relationship between the BGS and acoustic refractive index. In particular, we demonstrate the crucial role played by acoustic modes in anti-waveguide structures. The simulation results show that the Brillouin gain coefficient decreases with a decreasing acoustic index in the fiber core region. Furthermore, we experimentally measure the SBS threshold and BGS of the Al/Ge co-doped fiber to examine the validity of the numerical model. The simulated and experimental results are consistent.

Development of pulsed magnetic field assisted supersonic plasma spraying.

This study designs a pulsed magnetic field assisted supersonic plasma spraying (PM-SPS) device. The instrument is divided into magnetic field generation and spraying modules, and they are connected by a dual control system and professional fixture. The PM-SPS system is simple to operate and has no contact with the spraying process. In addition, it can achieve high field intensity and stable pulse frequency in a short time. It has a strengthening effect on the whole coating forming process. The porosity, roughness, hardness, and tribological properties of the coatings prepared using the PM-SPS system were improved. The reported experiments and results can be generalized to other coating applications, which require high quality surfaces.

Evaluation of Mutton Adulteration under the Effect of Mutton Flavour Essence Using Hyperspectral Imaging Combined with Machine Learning and Sparrow Search Algorithm.

The evaluation of mutton adulteration faces new challenges because of mutton flavour essence, which achieves a similar flavour between the adulterant and mutton. Hence, methods for classifying and quantifying the adulterated mutton under the effect of mutton flavour essence, based on near-infrared hyperspectral imaging (NIR-HSI, 1000-2500 nm) combined with machine learning (ML) and sparrow search algorithm (SSA), were proposed in this study. After spectral preprocessing via first derivative combined with multiple scattering correction (1D + MSC), classification and quantification models were established using back propagation neural network (BP), extreme learning machine (ELM) and support vector machine/regression (SVM/SVR). SSA was further used to explore the global optimal parameters of these models. Results showed that the performance of models improves after optimisation via the SSA. SSA-SVM achieved the optimal discrimination result, with an accuracy of 99.79% in the prediction set; SSA-SVR achieved the optimal prediction result, with an RP2 of 0.9304 and an RMSEP of 0.0458 g·g-1. Hence, NIR-HSI combined with ML and SSA is feasible for classification and quantification of mutton adulteration under the effect of mutton flavour essence. This study can provide a theoretical and practical reference for the evaluation and supervision of food quality under complex conditions.

Preparation of hollow-fiber nanofiltration membranes of high performance for effective removal of PFOA and high resistance to BSA fouling.

Nanofiltration (NF) process has become one of the most promising technologies to remove micro-organic combined water pollution. Developing a NF membrane material with efficient separation for perfluorooctanoic acid (PFOA) combined pollution is highly desired, this manuscript targets this unmet need specifically. In this work, hydrophilic SiO2 nanoparticles with various contents blended with carboxylic multiwalled carbon nanotube were used to modify poly (m-phenylene isophthal amide) (SiO2/CMWCNT/PMIA) hollow fiber NF membrane. The modified membrane with 0.1 wt% SiO2 doping exhibits way better fouling resistance with irreversible fouling ratio decreased dramatically from 18.7% to 2.3%, and the recovery rate of water flux increases significantly from 81.2% to 97.7%. The separation experiment results had confirmed that the modified membrane could improve the rejection from 97.2% to 98.6% for perfluorooctanoic acid (PFOA) and its combined pollution with bovine serum albumin (BSA). It is clear that this reported SiO2/CMWCNT/PMIA hollow fiber NF membrane potentially could be applied in water treatment. This research also provides a theoretical basis for efficiently removal of PFOA and its combined pollution by NF membrane.

Phase Transition Effect on Ferroelectric Domain Surface Charge Dynamics in BaTiO3 Single Crystal.

The ferroelectric domain surface charge dynamics after a cubic-to-tetragonal phase transition on the BaTiO3 single crystal (001) surface was directly measured through scanning probe microscopy. The captured surface potential distribution shows significant changes: the domain structures formed rapidly, but the surface potential on polarized c domain was unstable and reversed its sign after lengthy lapse; the high broad potential barrier burst at the corrugated a-c domain wall and continued to dissipate thereafter. The generation of polarization charges and the migration of surface screening charges in the surrounding environment take the main responsibility in the experiment. Furthermore, the a-c domain wall suffers large topological defects and polarity variation, resulting in domain wall broadening and stress changes. Thus, the a-c domain wall has excess energy and polarization change is inclined to assemble on it. The potential barrier decay with time after exposing to the surrounding environment also gave proof of the surface screening charge migration at surface. Thus, both domain and domain wall characteristics should be taken into account in ferroelectric application.

Microstructure and Mechanical Properties of Wire Arc Additively Manufactured MoNbTaWTi High Entropy Alloys.

High-temperature resistant high-entropy alloys (HEAs) have attracted extensive attention due to their excellent thermodynamic stability and mechanical properties, especially at high temperatures. However, a highly effective method for large-size HEAs is still desirable but challengeable. This research reported a facile yet effective strategy for MoNbTaWTi HEAs via in-situ wire arc additive manufacturing (WAAM). The wire was MoNbTaWTi cable-type welding wire (CTWW) consisting of one center wire and seven twisted peripheral wires. Then, additive manufacturing of MoNbTaWTi high entropy alloys (HEAs) was accomplished, and various analytical techniques studied the microstructures and mechanical properties of the overlaying formed layers. X-ray diffraction showed the overlaying formed layers to contain a single disordered BCC solid solution phase with high-temperature structural stability. In addition, the single-phase BCC structure was maintained from 0 to 1400 °C. The bottom of the overlaying formed layers was made of columnar cellular structure, and the upper part resembled "cauliflower-like" fine dendrite and equiaxed crystal structure. The hardness of the overlaying formed layers averaged 533 HV0.2 at room temperature. At 1000 °C, the hardness was around 110 HV1, close to the value of Inconel 718 alloy (125 HV1). The compressive strength of the overlaying formed alloy layers displayed no sensitivity towards change in temperature from 500 to 1000 °C. As the temperature rose from 500 to 1000 °C, the compressive strength changed from 629 to 602 MPa, equivalent to only a 27 MPa decrease. The latter was much higher than the strength of Inconel 718 alloy at the same temperature (200 MPa).